July 18, 2025

How Batteries Work: Energy Storage Chemistry

How Batteries Work: Energy Storage Chemistry

This podcast explains how batteries function as electrochemical devices that store and release electrical energy. They convert chemical energy into electrical energy through redox reactions. Key components include two electrodes, the anode (negative) and cathode (positive), separated by an electrolyte.

During charging, electrons move from the cathode to the anode, increasing chemical potential energy, while ions move through the electrolyte to balance the charge. When discharging, this stored chemical potential energy is converted back to electricity as electrons flow in the opposite direction through an external circuit, powering a device.

The overview highlights that rechargeable batteries allow this chemical reaction to be reversible, enabling repeated charge-discharge cycles. Factors like battery chemistry, capacity (measured in Ah or Wh), voltage, temperature, state of charge (SOC), charging/discharging rates, and cycle life affect performance and lifespan. Common types discussed include lead-acid and lithium-ion batteries, with the latter noted for its high energy density, long life, and efficiency.

Battery energy storage is crucial for integrating renewable energy sources (like solar and wind) into the electricity supply by storing excess energy for later use, stabilizing the grid, and reducing fossil fuel dependency, especially for electric vehicles. Research, particularly by the DOE Office of Science, focuses on improving materials for anodes, cathodes, and electrolytes to develop highly efficient and safe next-generation electrical energy storage solutions.